G'day Tex - couple of possibilities:
Your shellac is too old and hasn't been stored well.
Without going into big discussions, shellac flakes have a long shelf life if stored in a cool dark place. Best result for long term storage is in the fridge. Yours still may dissolve but could take around 3 days and even then I would be throwing it our.
You are using cheap supermarket or no name metho.
Best Metho is 100%IMS (industrial methylated spirits) next best 95%IMS. Anything not labelled with 100% or 95% isn't even worth trying as it can legally have up to around 42% water inclided in the mix. The main requirement for metho is that it shoild be OP (over proof alcohol) ie it must be able to burn. Meths will burn with around 42% water added.
Anyway the water prevents the flakes from dissolving.
I made a 120 batch of French Polish last week and it took around 1 hour for the flakes to fully dissolve in 100%IMS. Think I'd be throwing your stuff out.
Test for shellac when mix (fully dissolveded):.
Pour a small amount onto a piece of glass and if it isn't touch dry within 5 minutes it ain't no good. Chuck it out.
Test for metho:.
Pore a little metho into a bottle ad few drops of mineral turpentine to it and shake if it stays clear there's little or no water content if it there's any colour change at all there's water present if it goes milky it's rubbish only fit for washing windows with.
Hope this is of some help.
Cheers - Neil :U